Wake your PS5 from standby — and wake it straight into your user.
Power
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Wake from standby over the network. When the console is asleep, a Wake
button brings it back on, using Sony's discovery protocol (a PS5 does not
answer Wake-on-LAN). The setup panel spells out the three console settings
wake needs — Remote Play, plus Stay Connected to the Internet and Enable
Turning On PS5 from Network — because without any one of them the wake
fails silently. -
Wake & sign in. A plain wake stops at the user-select screen. Give the
console its Remote Play session keys and the wake also signs your user in,
bringing the console up on the home screen the way the official Remote Play
app does. If the account has a login passcode, the app says so rather than
hanging.